IRIDIUM



Iridium 3463
Photo by: Jose Ignacio Soto

Iridium

Overview

Indium is in Group 9 (VIIIB) of the periodic table. The periodic table is a chart that shows how elements are related to one another. Indium is a transition metal that is also part of the platinum family.

The metals in the platinum family are also known as the noble metals. They have this name because they do not react well with other elements and compounds. They appear to be "too superior" to react with most other substances. In fact, iridium is the most corrosion-resistant metal known. It is not affected by high temperatures, acids, bases, or most other strong chemicals. That property makes it useful in making objects that are exposed to such materials.

Iridium may be a key element in the puzzle of dinosaur extinction. Scientists search for iridium in the soil to track the impact of a giant meteor with the Earth 65 million years ago.

SYMBOL
Ir

ATOMIC NUMBER
77

ATOMIC MASS
192.217

FAMILY
Group 9 (VIIIB)
Transition metal
Platinum group

PRONUNCIATION
i-RI-dee-um

Discovery and naming

The platinum metals posed a difficult problem for early chemists. These metals often occurred mixed together in the earth. When a scientist thought that he was analyzing a sample of platinum, the sample often contained iridium, rhodium, osmium, and other metals as well. The work of French chemist Pierre-François Chabaneau is an example. In the late 1780s, the Spanish government gave its entire supply of platinum to Chabaneau to study. But Chabaneau's experiments puzzled him. Sometimes the platinum he worked with could be hammered into flat plates easily. At other times, it was brittle and shattered when hammered. Chabaneau did not realize that the "platinum" he was studying included various amounts of other noble metals.

In the early 1800s, a number of chemists worked to separate the platinum metals. One of those chemists was an Englishman named Smithson Tennant (1761-1815). Like so many others, Tennant became interested in chemistry at an early age. He is said to have made gunpowder to use in fireworks when he was only nine years old!

In 1803, Tennant attempted to dissolve platinum in aqua regia. Aqua regia is a mixture of two strong acids—nitric acid and hydrochloric acid. He found that most of the platinum metal dissolved, leaving a small amount of black powder. Other chemists had not bothered to study the powder. But Tennant did. He discovered that it had properties very different from those of platinum. He realized he had discovered a new element. He named it iridium, from the Greek goddess Iris, whose symbol is a rainbow. Tennant chose this name because the compounds of iridium have so many different colors. For example, iridium potassium chloride (K 2 IrCl 6 ) is dark red, iridium tri-bromide (IrBr 3 ) is olive-green, and iridium trichloride (IrCl 3 ) is dark green to blue-black.

Physical properties

Iridium metal is silvery-white with a density of 22.65 grams per cubic centimeter. A cubic centimeter of iridium weighs 22.65 times as much as a cubic centimeter of water. It is the most dense element known. Iridium has a melting point of 2,443°C (4,429°F) and a boiling point of about 4,500°C (8,130°F). Cold iridium metal cannot be worked easily. It tends to break rather than bend. It becomes more ductile (flexible) when hot. Ductile means capable of being drawn into thin wires. Therefore, it is usually shaped at high temperatures.

Small parts of indium can be found in meteorites. The Barrington Crater, in northern Arizona, was created about 25,000 years ago by a meteorite the size of a large house. It hit the ground at 9 miles per second, and created a hole .7 miles (1.2 kilometers) across and 590 feet (180 meters) deep.
Small parts of indium can be found in meteorites. The Barrington Crater, in northern Arizona, was created about 25,000 years ago by a meteorite the size of a large house. It hit the ground at 9 miles per second, and created a hole .7 miles (1.2 kilometers) across and 590 feet (180 meters) deep.

Chemical properties

Iridium is unreactive at room temperatures. When exposed to air, it reacts with oxygen to form a thin Layer of iridium dioxide (IrO 2 ).

At high temperatures, the metal becomes more reactive. Then it reacts with oxygen and halogens to form iridium dioxide and iridium trihalides. For example:

Occurrence in nature

Iridium is one of the rarest elements in the Earth's crust. It is thought to exist in two parts per billion. Interestingly, it is more abundant in other parts of the universe. Iron meteorites, for example, generally contain about 3 parts per million of iridium. Stony meteorites contain less iridium, about 0.64 parts per million.

Iridium usually occurs in combination with one or more other noble metals. Two common examples are osmiridium and iridosmine, combinations of iridium and osmium. The most important sources of iridium metal are Canada, South Africa, Russia, and the state of Alaska.

Tracking the fate of the dinosaurs

Iridium

W hy did the dinosaurs die out? This question has long been one of the most interesting and puzzling issues in science. What happened to make these huge reptiles disappear in such a short period of geological time?

One answer might be found in the Asteroid Disaster Theory. According to this theory, a huge asteroid struck the Earth's surface about 65 million years ago. The exploding asteroid threw enormous amounts of dust into the air. The dust blocked out sunlight for more than a year. Plants on the Earth's surface died. Dinosaurs who lived on those plants died out. So did the meat-eating dinosaurs who lived off the plant eaters.

But how is it possible to know if an asteroid really did hit the Earth's surface 65 million years ago? Scientists have now found an answer. In some parts of the Earth, they have found a layer of the Earth's crust that contains an unusually high level of iridium metal. Iridium rarely occurs on Earth. But it occurs much more commonly in meteors and asteroids. Scientists believe the iridium-rich layer was formed when an asteroid struck the Earth's surface. They believe the event occurred 65 million years ago. This "iridium clue" is a key, therefore, to understanding how dinosaurs disappeared from the Earth.

Iridium is one of the rarest elements in the Earth's crust. But it is more abundant in other parts of the universe. Iridium is found in meteorites.

Isotopes

Two naturally occurring isotopes of iridium exist, iridium-191 and iridium-193. Isotopes are two or more forms of an element. Isotopes differ from each other according to their mass number. The number written to the right of the element's name is the mass number. The mass number represents the number of protons plus neutrons in the nucleus of an atom of the element. The number of protons determines the element, but the

Did an asteroid—which contains iridium—kill off dinosaurs 65 million years ago? The asteroid Gaspra, photographed from the Galileo space probe, is shown here.
Did an asteroid—which contains iridium—kill off dinosaurs 65 million years ago? The asteroid Gaspra, photographed from the Galileo space probe, is shown here.
number of neutrons in the atom of any one element can vary. Each variation is an isotope.

About ten radioactive isotopes of iridium exist. A radioactive isotope is one that gives off radiation and changes into a new form. The only important radioactive isotope of iridium is iridium-192. This isotope has a half-life of 74 days. A half-life is the time it takes for one half of a sample to break down. Iridium-192 is used to make X-ray photographs of metal castings and to treat cancer.

Extraction

Iridium and the other platinum metals tend to occur together. A series of chemical reactions is used to separate one metal from the other. The other metals are then removed by other techniques. Very little iridium is produced each year, probably no more than a few metric tons.

Uses

The primary use of iridium is in the manufacture of alloys. An alloy is made by melting and mixing two or more metals. An alloy's properties differ from those of the elements that make it up. Iridium is often combined with platinum, for example, to provide a stronger material than the platinum itself. These alloys are very expensive and are used for only special purposes. For instance, the sparkplugs used in helicopters are made of a platinum-iridium alloy. Such alloys are also used for electrical contacts, special types of electrical wires, and electrodes.

The standard kilogram

B utter comes in one-pound or one-kilogram packages. But who decides how much "one pound" or "one kilogram" of butter is?

Every nation has a governmental office for weights and measures. The office maintains an "official" pound or kilogram. It is usually a piece of metal known to weigh exactly one pound or one kilogram. But how does each nation know exactly what size its official weight should be?

The official world standard for the kilogram is kept at the International Bureau of Weights and Measures in Paris. The standard is a piece of platinum-iridium metal stored in an airtight jar. The standard is made of platinum and iridium to protect it from reacting with oxygen and other chemicals in the air. In this way, the standard's weight will always remain exactly the same.

One kind of iridium catalyst is able to capture sunlight and turn it into chemical energy.

Iridium metal is increasingly being used as catalysts. Catalysts are substances that speed up a reaction without changing themselves. Iridium catalysts have been used in amazing new products. For example, one kind of iridium catalyst is able to capture sunlight and turn it into chemical energy. That process is similar to the one used by plants in photosynthesis. Finding a synthetic (artificial) way to make photosynthesis happen is one of the great goals of modern chemistry.

The heating of lead ores is called roasting, or smelting. The process results in pure lead.
The heating of lead ores is called roasting, or smelting. The process results in pure lead.

Niobium alloys are used in superconducting magnets. A superconductor has no resistance to an electric current Here, a small magnet levitates over a cooled slab of superconducting ceramic.
Niobium alloys are used in superconducting magnets. A superconductor has no resistance to an electric current Here, a small magnet levitates over a cooled slab of superconducting ceramic.

Neodymium is used in making lasers. This laser beam is reflected off mirrors and through filters.
Neodymium is used in making lasers. This laser beam is reflected off mirrors and through filters.

Magnified view of a lanthanum aluminate crystal
Magnified view of a lanthanum aluminate crystal

The glass in satellites often contains germanium. This satellite was launched in June 1990.
The glass in satellites often contains germanium. This satellite was launched in June 1990.

Three Mile Island nuclear reactor in Middletown, Pennsylvania. This was the site of a partial meltdown in 1979.
Three Mile Island nuclear reactor in Middletown, Pennsylvania. This was the site of a partial meltdown in 1979.

The neon lights of Las Vegas, Nevada, in the early 1990s.
The neon lights of Las Vegas, Nevada, in the early 1990s.

Stars use hydrogen as a fuel with which to produce energy. Antares—the brightest star in the constellation Scorpius—is shown here.
Stars use hydrogen as a fuel with which to produce energy. Antares—the brightest star in the constellation Scorpius—is shown here.

Gallium melts when held in the hand.
Gallium melts when held in the hand.

A farmer sprays nitrogen fertilizer on his rice field in California.
A farmer sprays nitrogen fertilizer on his rice field in California.

At high temperatures, magnesium burns with a blinding white light
At high temperatures, magnesium burns with a blinding white light

Space technology often uses alloys that are too expensive for everyday use. An example is the propulsion systems used for keeping satellites in place. Some of these systems use alloys made of indium and another platinum metal, rhenium. These alloys remain strong at high temperatures and are not attacked by fuels used in the systems.

Compounds

The compounds of indium have almost no practical applications. A few are used in coloring ceramics because of their striking colors.

Health effects

Scientists are not aware of any health benefits or risks associated with iridium.



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Apr 20, 2016 @ 1:01 am
Iridium what this use,and parpess,how to make chemical iridium and witch chemicals

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